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EP37778
Poster Title: Synthesis and characterization of o-phenolnaphthylimine and its application as metal sensor with β-cyclodextrin
Submitted on 18 Oct 2021
Author(s): K. Sivakumar*, G. Parinamachivayam, Sujay Chakravarty, A. Bharathi
Affiliations: Sri Chandrasekharendra Saraswathi Viswa Mahavidyalaya University (SCSVMV University)
This poster was presented at National Science day function at UGC-DAE-CSR, Kalpakkam
Poster Views: 604
Submitted on 18 Oct 2021
Author(s): K. Sivakumar*, G. Parinamachivayam, Sujay Chakravarty, A. Bharathi
Affiliations: Sri Chandrasekharendra Saraswathi Viswa Mahavidyalaya University (SCSVMV University)
This poster was presented at National Science day function at UGC-DAE-CSR, Kalpakkam
Poster Views: 604
Abstract: (i) O-phenolnaphthylimine (PNI) was synthesized by the condensation reaction of 2-hydroxynaphthalene-1-carbaldehyde and 2-aminophenol in ethanol with 90% yield.
(ii) The structural elucidation of the compound was done by using IR, 1H NMR, 13C NMR, and Mass spectral techniques.
(iii) The chemosensory ability of β-CD: PNI inclusion complex was investigated thoroughly for various metal cations and we found the emission of the complex showed a linear increase in the intensity for Al3+ with the linearity range of 20 µM to 300 µM For selectivity and Sensitivity analysis of β-CD: PNI inclusion complex with Al3+, Competitive experiment was carried out and it shows good sensing with Al3+ with the limit of detection of 44.9 µM and limit of quantification of 136 µM.
Summary: In summary, we developed a new Schiff base compound o-Phenolnaphthylimine (PNI) and it was characterized and confirmed by FT-IR, 1H NMR, 13C NMR and Mass spectral techniques. The β-CD: PNI complex shows good sensing towards Al3+ ion, using fluorescence spectroscopy.
References: 1. Soojin Kim, Jin Young Noh, Ka Young Kim, Jin Hoon Kim, Hee Kyung Kang, Seong-Won Nam, So Hyun Kim, Sungsu Park, Cheal Kim, and Jinheung Kim., Inorg. Chem. 51 (2012) 3597−3602.
2. K. Sivakumar et.al., Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 133 (2014) 73–79.
(ii) The structural elucidation of the compound was done by using IR, 1H NMR, 13C NMR, and Mass spectral techniques.
(iii) The chemosensory ability of β-CD: PNI inclusion complex was investigated thoroughly for various metal cations and we found the emission of the complex showed a linear increase in the intensity for Al3+ with the linearity range of 20 µM to 300 µM For selectivity and Sensitivity analysis of β-CD: PNI inclusion complex with Al3+, Competitive experiment was carried out and it shows good sensing with Al3+ with the limit of detection of 44.9 µM and limit of quantification of 136 µM.
Summary: In summary, we developed a new Schiff base compound o-Phenolnaphthylimine (PNI) and it was characterized and confirmed by FT-IR, 1H NMR, 13C NMR and Mass spectral techniques. The β-CD: PNI complex shows good sensing towards Al3+ ion, using fluorescence spectroscopy.
References: 1. Soojin Kim, Jin Young Noh, Ka Young Kim, Jin Hoon Kim, Hee Kyung Kang, Seong-Won Nam, So Hyun Kim, Sungsu Park, Cheal Kim, and Jinheung Kim., Inorg. Chem. 51 (2012) 3597−3602.
2. K. Sivakumar et.al., Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 133 (2014) 73–79.
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